Understanding crystallization pathways leading to manganese oxide polymorph formation

TitleUnderstanding crystallization pathways leading to manganese oxide polymorph formation
Publication TypeJournal Article
AuthorsChen B-R, Sun W, Kitchaev DA, Mangum JS, Thampy V, Garten LM, Ginley DS, Gorman BP, Stone KH, Ceder G, Toney MF, Schelhas LT
JournalNature Communications
Volume9
Issue1
Pagination2553
ISSN2041-1723
Abstract

Minor variations in synthesis conditions can redirect crystallization pathways through different nonequilibrium intermediates. Here, the authors present a theoretical framework to predict which polymorphs appear during MnO2 precipitation, which is validated by in situ X-ray scattering of reaction progression.

Notes

'doi: 10.1021/acsenergylett.0c01132\n - I.Am.Hydrogen'
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URLhttps://www.nature.com/articles/s41467-018-04917-y
DOI10.1038/s41467-018-04917-y
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